Product ID:DITHANE,M-45 FUNGICIDE
MSDS Date:01/01/1985
FSC:6840
NIIN:00-960-7244
MSDS Number: BFZHB

ROHM AND HAAS CO.

Emergency Phone: 215-592-3000

Cage: 77902

ROHM AND HAAS CO

PHILADELPHIA, PA 19106-2399 US

Telephone: 215-592-2521/215-592-3000

Cage: 77902

MANEB (SARA III)

CAS: 12427-38-2

RTECS: OP0700000

ZINC,(ETHYLENEBIS(DITHIOCARBAMATE)) (SEE SUPP DATA)

RTECS: ZH3325900

ETHYLENE THIOUREA (SARA III)

CAS: 96-45-7

RTECS: NI9625000

Fraction By Weight: 0.1%

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

INERT INGREDIENTS

Fraction By Weight: 19%

Effects of Overexposure:EYE CONT:INFLAM OF RETINA.SKIN:IRRIT.
INHALATION:CAN CAUSE PROGRESSIVE POISONING.

First Aid:INHAL:MOVE TO FRESH AIR.EYE CONT:FLUSH WITH WATER 15 MIN.
CONSULT A DR.SKIN:WASH AREA WITH SOAP & WATER.INGESTION:INDUCE
VOMITING IMMEDIATELY. CALL A DR.

Flash Point:280F/137C (TOC)
Extinguishing Media:CO2,DRY CHEMICAL,WATER FOG
Fire Fighting Procedures:SELF-CNTND BRTHG APP,WATER SPRAY TO COOL
CONTAINERS.
Unusual Fire/Explosion Hazard:TOXIC AND FLAMMABLE GASES ARE EVOLVED
WHEN MATERIAL IS HEATED ABOVE 176F/80C.

Spill Release Procedures:SWEEP OR SHOVEL INTO CONTAINERS FOR DISPOSAL
OR REWORK.KEEP DUSTING TO A MINIMUM.FLUSH CONTAMINATED AREA WITH A
LARGE AMOUNT OF WATER TO A CHEMICAL OR SANITARY SEWER.CONTAINING A
SETTLING PIT. KEEP SO LIDS OUT OF MUNICIPAL SEWER OR OPEN BODIES
WATER

Handling and Storage Precautions:STORE AT TEMPS BELOW 100F.KEEP AWAY
FROM FIRES,SPARKS & HOT SURFACES.STORE INSIDE A
COOL,DRY,WELL-VENTED AREA.KEEP CONT CLOSED WHEN NOT IN USE.
Other Precautions:WORKERS SHOULD TAKE A SHOWER AT THE END OF EACH
SHIFT.

Respiratory Protection:NIOSH/MSHA APPROVED RESP DEVICE IN ACCORD WITH
EXPOSURE OF CONCERN
Ventilation:MECHANICAL LOCAL EXHAUST
Protective Gloves:IMPERVIOUS
Eye Protection:SAFETY GLASSES
Other Protective Equipment:EYEWASH FACILITY,EMERGENCY SHOWER,CLEAN
OUTER CLOTH DAILY.
Supplemental Safety and Health
MAGANESE & ZINC COMPLEX-EBDC,A COORDINATION PRODUCT,COMPRISE 80% OF
PRODUCT BY WEIGHT.

HCC:N1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:GRAY-YELLOW POWDER;SLIGHT SULFUR ODOR.
Percent Volatiles by Volume:<3

Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS,ACID.
Stability Condition to Avoid:KEEP DRY,AVOID EXCESS HEAT AND IGNITION
SOURCES
Hazardous Decomposition Products:OXIDES OF
CARBON,NITROGEN,SULFUR,HYDROGEN SULFIDE,CARB DISUF

Waste Disposal Methods:IF PRACTICAL,LARGE AMOUNTS SHOULD BE RECOVERED
FOR USE,OTHERWISE DISPOSE OF IN A SECURE LANDFILL.SMALL AMOUNTS MAY
BE LANDFILLED ACCORDING TO LOCAL,STATE & FEDRAL REGS.RINSE EMPTY
CONTAINERS WITH WATE R DIRECT WASH TO A SANITARY OR CHEM SEWER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.